First of all you mast download Photoshop Lightroom 4 from this link :
https://www.adobe.com/cfusion/tdrc/index.cfm?product=photoshop_lightroom
Then open the setup file and run it ,Click NEXT button to began installing
Just wait a few minutes then click NEXT button
OK now if you have the serial key put it , If you don't click on I want to try
Then click on NEXT button
Put the serial in the field ,As shown in picture
Just wait a few minutes to complete installing
You are done click on FINISH button , Like in picture
Now click OK such As picture shown
Just wait a few minutes to run Photoshop installer
OK now click NEXT to began install Shield wizard for adobe Photoshop Lightroom
Then accept their terms agreement , After that click NEXT
After that click on next button
Now Click INSTALL button to began installing shield wizard
https://www.adobe.com/cfusion/tdrc/index.cfm?product=photoshop_lightroom
Then open the setup file and run it ,Click NEXT button to began installing
Just wait a few minutes then click NEXT button
OK now if you have the serial key put it , If you don't click on I want to try
Then click on NEXT button
Put the serial in the field ,As shown in picture
Just wait a few minutes to complete installing
You are done click on FINISH button , Like in picture
Now click OK such As picture shown
Just wait a few minutes to run Photoshop installer
OK now click NEXT to began install Shield wizard for adobe Photoshop Lightroom
Then accept their terms agreement , After that click NEXT
After that click on next button
Now Click INSTALL button to began installing shield wizard
Now click FINISH button, You are done ,Setup is Completed , Enjoy